Name: Radical and Ion-Pairing Strategies in Asymmetric Organocatalysis (en Inglés)
Price: 1044.87 MXN
Availability: InStock
Author: Vitale, Maxime R. ; Oudeyer, Sylvain ; Levacher, Vincent
ISBN: 9781785481277

Envío gratis

portada Radical and Ion-Pairing Strategies in Asymmetric Organocatalysis (en Inglés)

Formato

Libro Físico

Autor

Maxime R. Vitale

Sylvain Oudeyer

Vincent Levacher

Editorial

Iste Press - Elsevier

Idioma

Inglés

N° páginas

184

Encuadernación

Tapa Dura

Dimensiones

23.1 x 15.5 x 1.5 cm

Peso

0.41 kg.

ISBN13

9781785481277

Categorías

Química física
Química industrial e ingeniería química

Radical and Ion-Pairing Strategies in Asymmetric Organocatalysis (en Inglés)

Maxime R. Vitale (Autor) · Sylvain Oudeyer (Autor) · Vincent Levacher (Autor) · Iste Press - Elsevier · Tapa Dura

Libro Físico

$ 1,044.87

$ 2,089.74

Ahorras: $ 1,044.87

50% descuento

Envío normal

Origen: Reino Unido (Costos de importación incluídos en el precio)

Se enviará desde nuestra bodega entre el Miércoles 19 de Junio y el Lunes 01 de Julio.

Lo recibirás en cualquier lugar de México entre 1 y 3 días hábiles luego del envío.

Reseña del libro "Radical and Ion-Pairing Strategies in Asymmetric Organocatalysis (en Inglés)"

Considering the challenge of sustainability facing our society in the coming decades, catalysis is without any doubt a research area of major importance. In this regard, asymmetric organocatalysis, now considered a pillar of green chemistry, deserves particular attention. The first chapter of this volume examines the topic of asymmetric organocatalysis in light of radical chemistry. Recent important progress in this field has been attained by promoting the formation and harnessing the high reactivity of open-shell intermediates. Merging organocatalysis with radical chemistry has been the key to solving some longstanding bottlenecks, and has also significantly contributed to reinforcing the key role of organocatalysis in asymmetric catalysis. This chapter presents the most significant developments in this area, with a particular focus on asymmetric SOMO- and photoredox-organocatalyzed transformations. Chapter 2 focuses on quaternary ammonium salts (R4N+X-), especially chiral derivatives, and their behavior as unique catalysts in organocatalysis. Forming chiral ion-pairs capable of promoting asymmetric reactions, they also operate as unique "transporters" involved in phase transfer catalytic processes between liquid-liquid or liquid-solid systems. Furthermore, they offer unique opportunities when forming cooperative ion-paired entities R4N+X-, allowing a synergistic implication of the counter-ion X- either as Br nsted bases or Lewis bases. Specific design of such chiral catalysts in modern chemistry and better insight into their mode of activation facilitates efficient and unprecedented chemical transformations. This chapter provides an overview of the use of chiral quaternary ammonium salts in organocatalysis, emphasizing both general mechanistic aspects and the scope of this approach.