Name: Aspects of Homogeneous Catalysis: A Series of Advances (en Inglés)
SKU: 58559987
Price: 1026.06 MXN
Availability: InStock
Author: Ugo, R.
ISBN: 9789400963658

portada Aspects of Homogeneous Catalysis: A Series of Advances (en Inglés)

Aspects of Homogeneous Catalysis: A Series of Advances (en Inglés)

Formato

Libro Físico

Editorial

Springer

Autor

Ugo, R.

Idioma

Inglés

N° páginas

356

Encuadernación

Tapa Blanda

Dimensiones

24.4x17x1.9 cm

Peso

0.57 kg.

ISBN13

9789400963658

Categorías

Química física
Química industrial e ingeniería química
Ciencia de materiales

Aspects of Homogeneous Catalysis: A Series of Advances (en Inglés)

Ugo, R. (Autor) · Springer · Tapa Blanda

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Reseña del libro "Aspects of Homogeneous Catalysis: A Series of Advances (en Inglés)"

1. INTRODUCTION Although quite spectacular results have been obtained in the last few decades in the field of homogeneous transition metal catalyzed transformations of olefins and alkynes [1], reactions which could lead to heterocycles have been partly neglected. An obvious reason for this is that substrates containing heteroatoms such as N, 0 or S could coordinate the metal and suppress the catalytic activity. Nevertheless, some interesting early examples of transition-metal-catalyzed syntheses of heterocyclic compounds have been reported and these have been reviewed by C. W. Bird [2] . More recently the incorporation of CO, which enables esters and lactones 2 to be synthesized from olefinic starting materials, has begun to attract attention (see, for example, ref. [3]). The dominant role of palladium as the catalyst for the formation of O-containing heterocycles has been suggested to be associated with the relatively low strength of the Pd-O bond. Among the first examples of a nitrogen-containing heterocycle to be formed by homogeneous catalysis is the triazine shown in Equation 1 which is the product of the trimerization of benzonitrile in the presence of iron penta carbonyl or Raney- nickel [4] .