The 10-volume set LNCS 14254-14263 constitutes the proceedings of the 32nd International Conference on Artificial Neural Networks and Machine Learning, ICANN 2023, which took place in Heraklion, Crete, Greece, during September 26-29, 2023.The 426 full papers and 9 short papers included in these proceedings were carefully reviewed and selected from 947 submissions. ICANN is a dual-track conference, featuring tracks in brain inspired computing on the one hand, and machine learning on the other, with strong cross-disciplinary interactions and applications.