Theory of Electrophoresis and Diffusiophoresis of Highly Charged Colloidal Particles discusses the electrophoretic and diffusiophoretic motions of various colloidal entities, such as rigid particles, liquid droplets, gas bubbles, and porous particles, focusing on the motion-deterring double-layer polarization effect pertinent to highly charged particles, with the lowly charged ones serving as the limiting cases. Boundary effects such as those from a cylindrical pore, a solid plane, or an air-water interface are analyzed as well for the electrophoretic motion of the various particles considered. Dynamic electrophoresis is also explored and treated. The contents are suitable for researchers, graduate students, or senior college students with some basic background of colloid science and transport phenomena. As there is no closed-form analytical formula in general for the situation of highly charged particles, the results are presented with extensive figures and plots as well as tables under various electrokinetic situations of interest to facilitate the possible use of interested readers. Provides a reliable quantitative prediction of highly charged particles motion with easy-to-apply charts and in-depth understanding of the underlying mechanismsOffers an extensive treatment of direct quantitative predication for non-rigid systems, such as porous particles, liquid drops, and gels, which is especially valuable in proteins and DNA researchDiscusses highly charged systems with a nearby boundary of practical interests, such as a pore, a solid plane, or an air-water interface, which is of vital interest in fields such as microfluidic operations and biomedical engineeringAffords special attention to the polarization effect